Thermodynamic similarity parameter and acentric factor of alkali metals ww metal n eqs. Physical properties a guide to the physical, thermodynamic, and transport property data of industrially important. Box 500 500, 4600 dortmund 50, frg the thermodynamic activity of the alkali metals m in liquid mau alloys with mcs, rb, k and na has been. Ohse, handbook of thermodynamic and transport properties of alkali.
Pdf transport properties of fluids their correlation. Schmutzler physical chemistry ia, university of dortmund, p. Tables of thermodynamic properties of inorganic compounds. Pdf thermodynamic and transport properties of sodium liquid and. The yaws handbook of physical properties for hydrocarbons. A fusible alloy is a metal alloy capable of being easily fused, i. Liquid liquid immiscibility molten salt liquidliquid immiscibility ii. Oshe, handbook of thermodynamic and transport properties of alkali metals. The purpose of this handbook is to summarize and assess the vast amount of data and provide the practicing engineer and basic research worker with a comprehensive survey of current knowledge on structural, thermodynamic and transport properties of alkali materials. Emphasis has been given to the assessment of the critical point data.
Handbook of thermodynamic and transport properties of alkali metals, intern. In any given period of the periodic table, the atomic radii of the alkali metals is the largest, and the atomic radius increases as one moves down the group. Adiabatic and isothermal compressibility in the liquid state. Hightemperature thermodynamics of aqueous alkalimetal. The yaws handbook of physical properties for hydrocarbons and chemicals.
Thermodynamic properties of liquid metals and alloys. Journal of the national chemical laboratory for industry,tsukuba. Fusible alloys are commonly, but not necessarily, eutectic alloys. Related work thermodynamic and transport properties of alkali metals. Metals, international union of pure and applied chemistry, blackwell scientific. Selected values of thermodynamic properties of metals and alloys hardcover december 1, 1963 by r.
Accordingly, reduced collision integrals of k, rb, and cs metal vapors are obtained from the chapman. Od1643 us army correspondence course program 6 credit hours general the purpose of this subcourse is to introduce the student to the properties of metals, their characteristics, uses and identification codes. Handbook of thermodynamic and transport properties of. Pdf documents opened from your browser may not display or print as intended. With all of these considerations, the set of lms is reduced to mainly three categories, namely, alkali metals, heavy metals, and fusible metals. The alkali metals exhibit many of the physical properties common to metals, although their densities are lower than those of other metals. A hardwall potential function for transport properties of. Structure factor of liquid alkali metals in handbook of thermodynamic and transport properties of alkali metals. Using the values of the selfdiffusion coefficient, d hs, in the hardsphere fluid obtained by computer simulations, we have investigated a relationship between structural, thermodynamic, transport and surface properties of liquid metals near the melting point. Summary of physical properties for lithium, pb17li, and. The equation is presented in the reduced form, from which follows the singleparameter law of corresponding states with the thermodynamic similarity parametern.
Leibowitz, in handbook of thermodynamic and transport properties of alkali metals, edited by r. The densities of alkali metals are much lower when compared to other metals. Chemical looping combustion using the direct combustion of. A statistical mechanical based equation of state has been employed to calculate. Ourpresent quantitative knowledgeof forces in liquid sn, in, hg, pb, andal seems insufficient to predict their absorbtivity for vector 0. Solutions of non metals in alkali metals are treated in section 8, and in section 9 the binary and ternary alloy systems and their properties are summarized. Handbook of thermodynamic and transport properties of alkali metals editor roland w. Database of thermophysical properties of liquid metal coolants for. Hardwall potential function for transport properties of. The group of metals with values of aevo between 2 and 4 kcal cm3molh are considerably moreviscous than the alkali metals na to cs, indicating probability of some formation of hybrid interatomic orbitals. Lblanc research chemistry branch, aecl research, whiteshell laboratories, pinawa, mb, canada roe 1lo received 25 february 1991. Thermodynamic activity of alkali metals in alkali metal. Thermodynamic properties of minerals and fluids experiment in geosciences 2016 volume 22 n 1 39 properties of gases and liquids, 3d edition, mcgrawhill book company, new york, 592p.
Thermodynamics 1992, 24, 181203 hightemperature thermodynamics of aqueous alkali metal salts a preet p. Thermodynamic properties of sodium and potassium vapors at very high temperatures. The viscosity of liquid metals is investigated in a wide temperature range using the model potential of interatomic interaction. Thermodynamic and transport properties of sodium liquid and vapor. Measuring thermodynamic properties of metals and alloys. Download the latest version of adobe reader, free of charge.
From the given generalized equation, the expressions. Compilation of thermophysical properties of liquid lithium. Handbook of thermodynamic and transport properties of alkali metals. A modified cellular model of liquids is used to develop a method for calculating thermodynamic properties of liquid metals and their alloys, which are widely used in compact modern heat exchange equipment operating at high thermal flux densities. Values of the thermodynamic properties from the melting point up to boiling. Thermodynamic and transport properties for molten salts. An assessment of the experimentally determined vapour pressures of the liquid alkali metals handbook of thermodynamic and transport properties of alkali metals, 1st ed. This study demonstrates that the transport properties of alkali metals are determined principally by the repulsive wall of the pair interaction potential function. The alkali metals are the elements located in group ia of the periodic table. Paper open access estimation of the critical temperatures.
The structural, thermodynamic and transport properties and their methods of evaluation are critically assessed in sections 5 7. Ohse, editor, handbook of thermodynamic and transport properties of alkali metals, blackwell scientific publications, oxford 1985. Journal of noncrystalline solids 117118 1990 521524 521 northholland thermodynamic activity of alkali metals in alkali metalgold alloys ti. It is a common nitrogenous waste, particularly among aquatic organisms, and it contributes significantly to the nutritional needs of terrestrial organisms by serving as a precursor to food and fertilizers. The hardwall lennardjones lj 156 effective pair potential function is used to calculate the transport collision integrals. Union of pure and applied chemistry chemical data series no. Corresponding states theory and thermodynamic properties of liquid. The heat capacities of selected inorganic alkali metal compounds. Handbook of thermodynamic and transport properties of alkali metals qd172. Thermodynamic properties of minerals and related substances at 298.
Investigation of thermodynamic properties of heavy metals from melting and critical point properties. Handbook of thermodynamic and transport properties of alkali metals isbn editor roland w. Unlike other metals, the elements of the alkali metal group are soft substances and can be cut with a knife. Stable and unstable isotopes of tin 1 stable isotopes abundance% 112sn 0. Get a printable copy pdf file of the complete article 905k, or click on a page image below to browse page by page. Transport properties of fluids their correlation prediction and estimation.
A stable binary hydride, and the simplest pnictogen hydride, ammonia is a colourless gas with a characteristic pungent smell. Avoid contact with pure oxygen, strong alkalis, alkali metals, open flames and welding arcs, or other high temperature sources which induce thermal decomposition to irritating and corrosive hcl. Acentric factor of alkali metals, international journal of. A4 h36 1985 geisel 1 east heat capacities and entropies of organic compounds in the condensed phase, volume 2. Copland ati allvac monroe, north carolina 28111 nathan s.
Hultgren author see all formats and editions hide other formats and editions. The isotherm is intended to resolve the particular thermodynamic properties of alkali metals. Handbook of thermodynamic and transport properties of alkali metals, pp. Selected values of thermodynamic properties of metals and.
Shpilrain e e, yakimovich k a, fomin v a, skovorodjko s n and mozgovoi a g 1985b handbook of thermodynamic and transport properties of alkali metals ed r w ohse oxford. The handbook is intended for use by present and future designers in the liquid metals fast breeder reactor lmfbr program and by the engineering and scientific community performing other type investigation and exprimentation requiring hightemperature sodium and nak technology. Summary of physical properties for lithium, pb17li, and lifnbef2 coolants s. Purchase the yaws handbook of physical properties for hydrocarbons and chemicals 2nd edition. The main experimental techniques for measurements in the critical region are described. Foreward preface acknowledgements methods of evaluation errors and consistency symbols, units and conversion factors, key to notations basic. Control and safety of alkali metals structural properties of liquid alkali metals thermodynamic properties transport properties solution of non metals in alkali metals interalkali alloys ternary systems. Britain, engineering sciences data unit, 1981, science. The alkali metals are lithium, sodium, potassium, rubidium, cesium, and francium. Ammonia is a compound of nitrogen and hydrogen with the formula nh 3. Metalmolten salt systems principal data for alkali metalalkali halide mxm phase diagrams principal data for some alkaline earth metalhalide systems mx2m solubility of some transition and posttransition metals in their molten. Blackwell p 753 singwi k s and sjolander a 1960 phys. Measuring thermodynamic properties of metals and alloys with knudsen effusion mass spectrometry evan h.